The diterpene alkaloids: the pyrolysis and absolute configuration of heteratisine
β Scribed by R. Aneja; S.W. Pelletier
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- French
- Weight
- 388 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The absolute configuration of the pavine alkaloid (-)-argemonine (13 was firmly determined by chemical degradation,2 and through a non-empirical analysis of the cd spectrum. 3 The results of an empirical ord study were also interpreted as leading to the absolute configuration depicted. 4
The rhoeadine alkaloids are dextrorotatory bases found only in Papaver species (Papaveraceae); three typical examples being (+)-glaudine, (+)-epiglaudine and (+)-oreodine.2 The relative stereochemistry at C-l and C-2 was obtained from nmr coupling constants,
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The recent articles by Pelletier 2B3 on the relative stereochemistry of the diterpene alkaloids of the veatchineatisine class4 prompt us to record some of our own results in this field. As will be shown below, our investigations establish the absolute configuration of the C/D ring juncture and by in