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The absolute configuration of the rhoeadine alkaloids

✍ Scribed by Maurice Shamma; J.L. Moniot; Wan Kit Chan; Koji Nakanishi

Publisher: Elsevier Science
Year: 1971
Tongue: French
Weight: 158 KB
Volume: 12
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)97501-x

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✦ Synopsis

The rhoeadine alkaloids are dextrorotatory bases found only in Papaver species (Papaveraceae);

three typical examples being (+)-glaudine, (+)-epiglaudine and (+)-oreodine.2

The relative stereochemistry at C-l and C-2 was obtained from nmr coupling constants,

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