The distribution of solubilisate molecules in micellar assemblies
β Scribed by Tom F. Hunter
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 424 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The dlstrlbutlon h% governmg the statxstlcs of solublhsed molecules UI rmcellar assembhes IS commonly assumed to be the Poisson law. Other dlstributlon iaws are shown to be possible and cases where there IS a hmlt to the number of solubllrsed molecules m any one mxeile are evammed It 1s argued that for large, essentrally water-msoluble solublirutes non-Poisson statlstxs are hkefy, wth ~term~cei~r ovation taking place as clusters of a soiubihsed molecule pfus a number of molecules (or Ions) of the mtcelhr compound.
π SIMILAR VOLUMES
The excited state behaviour of pyrene and naphthalene was examined in functional surfacmt units in which silver ions, A$, served as the micellar counterions. Throwh local orgaoization present in these molecular aggregates, A$ can exert a very efficient external heavy atom effect leading to drastic e