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The distribution of solubilisate molecules in micellar assemblies

✍ Scribed by Tom F. Hunter


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
424 KB
Volume
75
Category
Article
ISSN
0009-2614

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✦ Synopsis


The dlstrlbutlon h% governmg the statxstlcs of solublhsed molecules UI rmcellar assembhes IS commonly assumed to be the Poisson law. Other dlstributlon iaws are shown to be possible and cases where there IS a hmlt to the number of solubllrsed molecules m any one mxeile are evammed It 1s argued that for large, essentrally water-msoluble solublirutes non-Poisson statlstxs are hkefy, wth ~term~cei~r ovation taking place as clusters of a soiubihsed molecule pfus a number of molecules (or Ions) of the mtcelhr compound.


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