๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The dissociative ionization of C2H2. The C+, C2+ and CH2+ dissociation channels. The vinylidene ion as a transient?

โœ Scribed by R. Locht; M. Davister

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
939 KB
Volume
195
Category
Article
ISSN
0301-0104

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Theoretical study of the C๎—ธH bond dissoc
Theoretical study of the C๎—ธH bond dissociation energies of CH4, C2H2, C2H4, and H2C2O
โœ Charles W. Bauschlicher Jr.; Stephen R. Langhoff ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 554 KB

The successive C-H bond dissociation energies of CH,, &Hz. C2H4, and H&O (ketene) are determined using large basis sets and a high level of correlation treatment. For CHI, C2H2, and C2H4 the computed values are in excellent agreement with experiment. Using our results we recommend 107.9 +2.0 and 96.

The C๎—ธH dissociation energy of C2H6
The C๎—ธH dissociation energy of C2H6
โœ Charles W. Bauschlicher Jr.; Harry Partridge ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 429 KB

The C-H bond energy in C2H 6 is computed to be 99.76 \_+ 0.45 kcal/mol, which is in excellent agreement with the most recent experimental values. The calculation of the C-H bond energy by direct dissociation and by an isodesmic reaction is discussed.

The generation and identification of the
The generation and identification of the transient vinylidene cation, [H2C๎—ปC]+.
โœ John L. Holmes; Jan E. Szulejko ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 255 KB

## The vinylidene cation, [CHyC] t,wasgenerared as a wmsient species by collisionally induced chqe revers31 of the corresponding anion. The cotlisionallf induced mass spectrum of the transienr (CHz=C]z is chvactzrisrically different from that of ionised acetylene.