𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The CH dissociation energy of C2H6

✍ Scribed by Charles W. Bauschlicher Jr.; Harry Partridge

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
429 KB
Volume
239
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The C-H bond energy in C2H 6 is computed to be 99.76 _+ 0.45 kcal/mol, which is in excellent agreement with the most recent experimental values. The calculation of the C-H bond energy by direct dissociation and by an isodesmic reaction is discussed.

📜 SIMILAR VOLUMES

The kinetics of the gas-phase reaction b
The kinetics of the gas-phase reaction between iodine and phenylsilane and the bond dissociation energy D(C6H5SiH2H)
✍ M. Barber; A. M. Doncaster; R. Walsh 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 418 KB

The title reaction has been investigated in the temperature range of 490-573 K. Initial reactant pressures were varied in the range of 0.2-5.2 torr (12) and 2-20 torr (C&,SiH3). The rate of iodine consumption, monitored spectrophotometrically, was found to obey both by initial rate and integrated e

Cl-atom transfer from CFCl3 to the c-C6H
Cl-atom transfer from CFCl3 to the c-C6H11 radical. An indirect estimation of the CFCl2Cl bond dissociation energy
✍ G. Baruch; L. A. Rajbenbach; A. Horowitz 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 342 KB

The C1-transfer reaction between CFC13 and c-CsH11 radicals (R) was studied in liquid cyclohexane (RH). The Arrhenius parameters for C1 abstraction were determined in the RH-CFC13 system versus the termination reaction between cyclohexyl radicals and competitively versus addition to C2CI4 in the RH-

Theoretical study of the CH bond dissoc
Theoretical study of the CH bond dissociation energies of CH4, C2H2, C2H4, and H2C2O
✍ Charles W. Bauschlicher Jr.; Stephen R. Langhoff 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 554 KB

The successive C-H bond dissociation energies of CH,, &Hz. C2H4, and H&O (ketene) are determined using large basis sets and a high level of correlation treatment. For CHI, C2H2, and C2H4 the computed values are in excellent agreement with experiment. Using our results we recommend 107.9 +2.0 and 96.

An experimental determination of the hea
An experimental determination of the heat of formation of C2 and the CH bond dissociation energy in C2H
✍ Randall S. Urdahl; Yihan Bao; William M. Jackson 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 337 KB

The rotational cutoff levels of C,( B' 'Z:, u" = 1,2), produced in the multiphoton dissociation of jet-cooled acetylene at 193 nm, have been measured using laser-induced fluorescence. This data is used to calculate the values AHf,,(C2) = 194.8iO.5 kcal/ mol and D,(CC-H) = 112.0 kO.8 kcal/mol, in exc