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The Dissociation Enthalpies of Terminal (N—O) Bonds in Organic Compounds

✍ Scribed by William E. Jr. Acree; Geoffrey Pilcher; Maria D. M. C. Ribeiro da Silva

Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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## Acidities of Stable Simple Enols and Bond Dissociation Enthalpies of Their H-O Bonds in DMSO. -The values of acidity and bond dissociation enthalpy of enols (I) are discussed in terms of steric and electronic effects. For the 1,1-dimesityl derivatives the pKHA values increase with the bulk of t