The D O values for AIH 2 and AIAr are computed using the coupled cluster approach in conjunction with large basis sets. Basis set superposition and spin-orbit effects are accounted for, as they are significant due to the small binding energy. The computed dissociation energy (D o) for AIAr is 114 cm
The dissociation energies of gaseous Br2 and I2
โ Scribed by R.F. Barrow; D.F. Broyd; L.B. Pederson; K.K. Yee
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 153 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
Near rotational analyses have been made of the B3no+u-S1
zfi'systems of 79&Z, "BrZ and lt712. The density
๐ SIMILAR VOLUMES
D;(PrO) and Dt(NdO) have been measured mass spectrometrically and found to be 736-4 f 126 kJ/mol and 697.0 F 12.6 kJ/mol, respectively. Ionic contnbutions to bonding in these molecules are discussed.
The kinetics of the title reactions have been studied using the discharge-flow mass spectrometic method at 296 K and 1 torr of helium. The rate constant obtained for the forward reaction (1), using three different experimental approaches (kinetics of Br Br ฯฉ IBr : I ฯฉ Br 2 consumption in excess of
The kinetics and equilibrium of the gas-phase reaction of CHaCFZBr with IZ were studied spectrophotometrically from 581 to 662ยฐK and determined to be consistent with the following mechanism: KIZ
An analysis of thermochemical and kinetic data on the bromination of the halomethanes CH, ,X,, (X = F, C1, Br; n = 1-31, the two chlorofluoromethanes, CH,FCI and CHFCl,, and CH,, shaws that the recently reported heats of formation of the radicals CH2C1, CHClz, CHBr2, and CFC12, and the C-H bond diss