The diffusion coeficient, D, of CuSO, in aqueous solution was determined at 298.1 K by chronopotentiometry and also with a rotating disc electrode using the mixed control Levich equation. For 0 < [CuSO,] < 0.05 moldm-3,D = 17.35 &O.iS-(5.3\* l.4)[CuS0,]'~Z} x 10-'DmZs-', at a constant ionic strength
โฆ LIBER โฆ
The dissociation constant of copper sulphate in aqueous solution
โ Scribed by Davies, W. G.; Otter, R. J.; Prue, J. E.
- Book ID
- 120178328
- Publisher
- Royal Society of Chemistry
- Year
- 1957
- Weight
- 364 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0366-9033
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Galvanostatic single-pulse, rotating-disc and chronopotentiometric measurements on etched polycrystalline copper electrodes in semimolar mixed solutions of CuS04, MgSOL and HISO at 25ยฐC have yielded kinetic parameters and specific rate data for either of the two consecutive chargetransfer steps of t