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The direct process in the spin-lattice relaxation of DPPH in a rigid matrix

✍ Scribed by I.M. Brown; D.J. Sloop


Book ID
107731281
Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
193 KB
Volume
1
Category
Article
ISSN
0009-2614

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Spin-lattice relaxation of the biphenyl
✍ I.M. Brown; D.J. Sloop; D.P. Ames πŸ“‚ Article πŸ“… 1967 πŸ› Elsevier Science 🌐 English βš– 386 KB

## Measurements of the spin-lattice relaxation time of the biphenyl anion radical in a rigid matrix of 2-methyl-tetrahydrofuran indicate tnat the Van Vleck direct process is followed from 1.25oK to 3.5oK and a Raman process giving a T2 dependence dominates from 350K to 810K. A concentration depend