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The Dimroth rearrangement. Part XVI. A new general synthesis and rearrangement of C-alkylated 1,6-dihydro-6-imino-1-methylpyrimidines

โœ Scribed by Brown, Desmond J.; Ienega, Kazuharu


Book ID
121080385
Publisher
Royal Society of Chemistry
Year
1974
Weight
883 KB
Category
Article
ISSN
1472-7781

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Synthesis and Dimroth Rearrangement of 6-Cyano-1,2,4-triazolo[4,3a]pyrimidin-5-and 7-ones. A Novel Alkylation with Orthoesters and a New Participation of the Cyano Group in the Rearrangement. -Formic acid and triethyl orthoformate react with 2-hydrazinopyrimidin-4-ones (I) and (VI) to furnish triazo