A general approach to the synthesis of 1,6-dicarbonyl substrates. New applications of base-accelerated oxy-Cope rearrangements
✍ Scribed by Evans, David A.; Baillargeon, David J.; Nelson, John V.
- Book ID
- 127353951
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 363 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0002-7863
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## Abstract Reaction of ketooximes containing α‐methylene group with chloramine‐T followed by treatment with tri‐ethylamine leads to the formation of α‐nitrosoolefins __via__ α‐nitrosochloride, which can react __in situ__ intermol‐ecularly with olefinic compounds to produce 5,6‐dihydro‐4__H__‐1,2‐o