The crystal structure of lead cyanamide, PbNCN, has been refined on the basis of a single crystal grown from solution. PbNCN crystallizes in space group Pnma (Z = 4) with a = 555.66(4) pm, b = 386.77(2) pm, and c = 1173.50(8) pm. The cyanamide anion exhibits CΒ±N bond lengths of 116 pm and 130 pm, an
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The dimers of cyanamide
β Scribed by J.B. Moffat
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 321 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0022-2860
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A range of radicals have been obtained from pure H,NCN and MezNCN and from solid solutions favouring electron capture or electron loss. Those well characterized by ESR spectroscopy include H,N(H)C-I$ Me,fiCN+ and Me2N..