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The dielectric constant of water: influence of the quadrupole moment

โœ Scribed by C.G. Joslin


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
317 KB
Volume
91
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


WC cummc the suggestion that the very high diclcctnc constant of water is associated with the absence of a signilicant component of the quadmpolc tensor along the directIon of Lhc dipole moment WC liid that although ozz = 0, Lhcsc IS II


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## Abstract When carboxylic acids are dissolved in trialkylamines, the dipole moments ฮผ~ab~ of the 1/1 complexes increase when the molefraction of the acid becomes greater. This is due to the enhancement of the dielectric constant of the medium which affects the transfer constant K~t~ of the proton