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The dielectric constant of polar hard spheres

โœ Scribed by D. Isbister; G.P. Morriss

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
625 KB
Volume
122
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

A Monk Carlo swdy of [he slalic dielctxic consLant of a fluid of polar hard spheres is presented. For fined values of lhe dipole moment. it is found that Ihe dielectric constant is essentially independent of Ihc charge scparatinn. This esIablishes that lhe decrease in dielceuic constam for polar hard dumbbells as the bond length increases is due LO the shape forces alone. The sire-sire radial distribution functions for the polar hard-sphere fluid are continuous functions of r. The usual disconlinuily associated with the hard-sphere poleminI is absent.

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