๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The Diastereoselective Synthesis of Quaternary Substituted Thioindolines from Sulfur Ylide Intermediates

โœ Scribed by Nyong, Abijah M.; Rainier, Jon D.

Book ID
125896482
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
158 KB
Volume
70
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Diastereoselective synthesis of quaterna
Diastereoselective synthesis of quaternary substituted thioindolines from sulfur ylide intermediates
โœ Alexei V Novikov; Amir Sabahi; Abijah M Nyong; Jon D Rainier ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 267 KB

We have examined the coupling reactions of 2-thioindoles with vinyl diazoacetates in the presence of Rh(II) catalysts. While attempted enantio-and/or diastereoselective couplings using chiral catalysts and/or chiral auxiliaries on the vinyl diazoacetate have been largely unsuccessful, substrates hav

Catalytic sulfur ylide reactions: Use of
Catalytic sulfur ylide reactions: Use of diazoacetamides for the diastereoselective synthesis of glycidic amides
โœ Varinder K. Aggarwal; Paul Blackburn; Robin Fieldhouse; Ray V.H. Jones ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 183 KB

Diazoacetamides react with aldehydes in the presence of catalytic quantities of Cu(aeac)2 (5 tool%) and tetrahydrothiophene (20 tool%) to give glycidic amides in good yields and high diastercoselectivity.