✍ Scribed by Naoki Tanifuji; Honghua Huang; Yoko Shinagawa; Keiji Kobayashi
No coin nor oath required. For personal study only.
Photoirradiation of tris(2-benzo[b]
thienyl)methane in acetonitrile resulted in the unexpected formation of a cyclopropane compound, which is rationalized based on the di-p-methane rearrangement including two unsaturated bonds of the benzo[b]thiophene rings.
📜 SIMILAR VOLUMES
## Abstract The triplet photosensitization of the β, γ, β^1^, γ^1^‐dienone 2 leads to the formation of the DPM isomer 6 and the two ODPM isomers 7 and 8 in a ratio of 35:17:10. This is the first reported example of a substrate which exhibits intramolecular competition as demonstrated by the occurre
Polar substituent effects on the aromatic ring emerge in the regioselectivity of the di-n-methane rearrangement of the title compounds when they possess the structural feature of including the bridgehead carbon in a saturated ring; the importance of the environment at the bridgehead carbon is pointe