𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Triplet versus Singlet Photoreaction Mechanism in the Barrelene Di-π-methane Rearrangement

✍ Scribed by Frutos, Luis M.; Sancho, Unai; Castaño, Obis

Book ID
127098924
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
100 KB
Volume
6
Category
Article
ISSN
1523-7060

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Intramolecular competition between the d
Intramolecular competition between the di-π-methane and the oxa-di-π-methane rearrangements in a triplet-excited β, γ, β1, γ1-dienone.
✍ Reinout van der Veen; Cornelis Kruk; Hans Cerfontain 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 171 KB

## Abstract The triplet photosensitization of the β, γ, β^1^, γ^1^‐dienone 2 leads to the formation of the DPM isomer 6 and the two ODPM isomers 7 and 8 in a ratio of 35:17:10. This is the first reported example of a substrate which exhibits intramolecular competition as demonstrated by the occurre