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The deuterium effect on the triplet radiative decay rate of aromatic molecules

✍ Scribed by Philip M. Johnson; Mario C. Studer

Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 435 KB
Volume: 18
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(73)80184-8

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✦ Synopsis

of.reIative quantum yields of pkosphorescene have been made for naphthalene versus perdeuteranaphthalenc and for toluene versus perdeutcrotoluene, all contained in argon crystds at 20°K. In combination with tripIet lifetime measurements these quantum yield ratios give the ratios of radiative tripfet decay rates. No radiative denterium effect is found for toluene and only a small effect is seen in naphthalene in contrast to the rather large radiative deuterium effect seen for naphthalene in EPA by Li and Lim.

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