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On the low-lying triplet of the water molecule and its luminescent decay

✍ Scribed by A. Bernas; T.B. Truong

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
394 KB
Volume
29
Category
Article
ISSN
0009-2614

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✦ Synopsis

Due to a significant discrepancy between theoretical calculations and euperimcntal exit&on data, the position of the low-lying triplet state df water has been much debated in recent years. WC now report that the corresponding transition (= 4.0 eV) can be observed also in emission upon charge neutralization in r-irradiated ordinary and heavy ices and also by photosensitization fram the mercury 3PI or 3Po state. The observed radiative decay is cha:acterized by an emission X,, at 380-385 nm.

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