## Abstract The relative importance of bond strength, steric effects, and polarity in determining the rate and orientation of free radical subsitution and free radical addition reaction is considered. The factors which control substitution reaction (radical transfer reaction) are gathered together
The determination of radical concentrations and reactivities in chemical reactions
β Scribed by H.W. Melville
- Publisher
- Elsevier
- Year
- 1948
- Weight
- 385 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1062-2896
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Semi-empirical calculations of isolated diamines and model anhydrides and of their interaction energy, AE, have been made. Reactivity indices of diamines and dianhydrides (atom charges, characteristics of frontier orbitals) have been found. Analysis of the AE components has shown that chemical struc
## on the occasion of his 65th birthday The reaction mechanism is the detailed, step-by-step description of a chemical reaction. Most chemical reactions take place through a complex sequence of steps via reactive intermediates. The most important reactive intermediates in organic chemical reaction