The derivation of relativistic corrections to the hamiltonian for two electrons
β Scribed by E.A. Moore
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 207 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Relativistic corrections to the bond lengths, dissociation energies and harmonic frequencies of RF, RbF and CsF have been obtained at the self-consistent field level by dissociating to ions. The relativistic corrections to the bond lengths, harmonic frequencies and dissociation energies to the ions
The exact pi-electron hamiltonian isderived from the full many-electron Schriidinger equation. The derivation employs techniques which also enable the developmenr of open shell generalized perturbation theory. The parameters occurring in the pi-hamiltonian are therefore amenable to cakulation using