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Relativistic corrections to the properties of the alkali fluorides

โœ Scribed by Kenneth G. Dyall; Harry Partridge

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
256 KB
Volume
206
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Relativistic corrections to the bond lengths, dissociation energies and harmonic frequencies of RF, RbF and CsF have been obtained at the self-consistent field level by dissociating to ions. The relativistic corrections to the bond lengths, harmonic frequencies and dissociation energies to the ions are very small, due to the ionic nature of these molecules and the similarity of the relativistic and nonrelativistic ionic radii.

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