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The decomposition reaction of the dialene radical anion [R2Al&.;−AlR2]− in DME(II): crystal strctures of the aluminum glycolates [R2Al(OCH2)2]K(DME) and R2Al(OCH)2)2 Al(R)(OCH2)2AlR2 (R = CH(SiMe3)2)

✍ Scribed by Werner Uhl; Rolf Gerding; Annegret Vester


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
763 KB
Volume
513
Category
Article
ISSN
0022-328X

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A Methylene-Bridged Dialuminium Compound
✍ Werner Uhl; Frank Hannemann; Wolfgang Saak; Rudolf Wartchow 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 304 KB 👁 2 views

Sodium nitrite (NaNO 2 ) dissolves readily in THF, when the aluminium atom to form a five-membered Al 2 CNO heterocycle. The second oxygen atom of the nitrite anion is not methylene-bridged dialuminium compound R 2 Al-CH 2 -AlR 2 [R = CH(SiMe 3 ) 2 ] 1 with two coordinatively unsaturated affected. S