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The Decomposition of Molybdenum Hexacarbonyl on Thin Alumina Films at High Temperatures: Formation and Reduction of Carbides

✍ Scribed by M. Kaltchev; W.T. Tysoe


Book ID
112256241
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
82 KB
Volume
196
Category
Article
ISSN
0021-9517

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Interaction of molybdenum hexacarbonyl w
✍ Y. Wang; F. Gao; W.T. Tysoe πŸ“‚ Article πŸ“… 2005 πŸ› Elsevier Science 🌐 English βš– 1014 KB

The reaction of Mo(CO) 6 with thin films of dehydroxylated alumina grown on a Mo(1 0 0) substrate above 500 K is studied in ultrahigh vacuum using temperature-programmed desorption and Auger and X-ray photoelectron spectroscopies. This results in the formation of a molybdenum carbide that incorporat