The crystal structure of silver(II) - bis(pyridine-2,3-dicarboxylate) dihydrate
β Scribed by M.G.B. Drew; R.W. Matthews; R.A. Walton
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 109 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0020-1650
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A mononuclear copper(II) complex, [Cu(dmpp)(OCN) 2 (H 2 O)], was synthesized using 2,6-bis (3,5dimethylpyrazolyl) pyridine (dmpp) and cyanate anion (OCN), and characterized by single crystal X-ray diffraction. The coordination around the Cu atom is a distorted square-pyramid involving three N atoms
Palladium(II) azide (1) was synthesized by reaction of palladate(II) (3) were synthesized by a high-yield reaction. Both were characterized by X-ray structural analysis, IR, palladium nitrate and sodium azide. 1 was characterized by AAS, IR, and 14 N-NMR spectroscopy. Bis(azido)bis(pyridine)-Raman,