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Characterization of Palladium(II) Azide and Crystal Structure of Bis(azido)bis(pyridine)palladium(II) and Tetramminepalladium Tetraazidopalladate(II)

✍ Scribed by Wolfgang Beck; Thomas M. Klapötke; Jörg Knizek; Heinrich Nöth; Thomas Schütt

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
204 KB
Volume
1999
Category
Article
ISSN
1434-1948

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✦ Synopsis

Palladium(II) azide (1) was synthesized by reaction of palladate(II) (3) were synthesized by a high-yield reaction.

Both were characterized by X-ray structural analysis, IR, palladium nitrate and sodium azide. 1 was characterized by AAS, IR, and 14 N-NMR spectroscopy. Bis(azido)bis(pyridine)-Raman, and NMR spectroscopy. palladium(II) (2) and tetramminepalladium tetraazidothere is water coordinated. The IR spectrum of the ex-

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