Coordination Behaviour of the New Multidentate Ligand 3,5-Bis(dimethylaminomethyl)pyridine with Palladium(II) and Platinum(II) Metal Centres
✍ Scribed by María-Cristina Lagunas; Robert A. Gossage; Wilberth J. J. Smeets; Anthony L. Spek; Gerard van Koten
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 460 KB
- Volume
- 1998
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
Pyridine ligands / Bidentate bridging ligands / Palladium / Platinum / N ligands
The synthesis of the new potentially tridentate ligand 3,5-contain ligand 3 bonded to 2 metal centres by bridging through coordination of one trialkyl N donor atom and the bis(dimethylaminomethyl)pyridine ( 3) is described. Coordination chemistry of this ligand has been investigated with pyridinic N atom. The solid-state structure of a ligand bridged Pd dimer has been elucidated by single-crystal X-Pd II and Pt II precursor compounds. Both a bidentate bridging bonding motif and a monodentate bonding mode is obser-ray diffraction and corroborates with the solid-state IR data that suggested a trans-PdCl 2 unit was present. ved. The latter compounds incorporate 3 by coordination through the pyridinic N atom only. The former complexes