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The crystal structure of Cu4Bi5S10 and its relation to the structures of hodrushite and cuprobismutite

✍ Scribed by Mariolacos, K. ;Kupčík, V. ;Ohmasa, M. ;Miehe, G.

Book ID
117859388
Publisher
International Union of Crystallography
Year
1975
Weight
670 KB
Volume
31
Category
Article
ISSN
0567-7408

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Structures and Conductivities of the Qua
Structures and Conductivities of the Quaternary A/Bi/Cu/S Phases KBi2CuS4 and A3Bi5Cu2S10 (A=Rb, Cs)
✍ Yuting Yang; Paul Brazis; Carl R. Kannewurf; James A. Ibers 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 265 KB

The compounds KBi2CuS4, Cs3Bi5Cu2S10, and Rb3Bi5Cu2S10 were prepared by stoichiometric reactions of the corresponding alkali-metal sul5des with Bi, Cu, and S at 1123 K. KBi2CuS4 crystallizes as a racemic twin in space group Cmc21 of the orthorhombic system with four formula units in a cell of dimens