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The crystal structure of (AsPh4)2[OsN(OH)(CN)4]

✍ Scribed by Hendrik J. Westhuizen; Stephen S. Basson; Johann G. Leipoldt; Walter Purcell


Book ID
105024549
Publisher
Springer
Year
1994
Tongue
English
Weight
249 KB
Volume
19
Category
Article
ISSN
0340-4285

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Direct photolytic route to trans-Cr(CO)4
✍ Christina L Bergstrom; Rudy L Luck πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 139 KB

The preparation of trans-Cr(CO) 4 (AsPh 3 ) 2 is accomplished in reasonable yield by the direct photolysis of a solution of Cr(CO) 6 and an excess of AsPh 3 in heptane. The structures of cis-Mo(CO) 4 (AsPh 3 ) 2 and cis-W(CO) 4 (AsPh 3 ) 2 are reported. These are found to be isostructural and consis