✦ LIBER ✦

Direct photolytic route to trans-Cr(CO)4(AsPh3)2 and crystal structures of cis-Mo(CO)4(AsPh3)2 and cis-W(CO)4(AsPh3)2

✍ Scribed by Christina L Bergstrom; Rudy L Luck

Book ID: 104138514
Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 139 KB
Volume: 318
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(01)00404-2

No coin nor oath required. For personal study only.

✦ Synopsis

The preparation of trans-Cr(CO) 4 (AsPh 3 ) 2 is accomplished in reasonable yield by the direct photolysis of a solution of Cr(CO) 6 and an excess of AsPh 3 in heptane. The structures of cis-Mo(CO) 4 (AsPh 3 ) 2 and cis-W(CO) 4 (AsPh 3 ) 2 are reported. These are found to be isostructural and consist of distorted octahedral geometries with As M As angles of 102.56(2) and 102.62(2)°for M =Mo and W, respectively. The Mo As distances of 2.6428(9) and 2.6489(9) A , are significantly longer than those in the W analogue at 2.6384(6) and 2.6361(6) A , . On the basis of a comparison to literature data, the AsPh 3 ligands in these molecules can be described as extremely compressed.

📜 SIMILAR VOLUMES

Synthesis and molecular structure of the

Synthesis and molecular structure of the borido cluster Fe4(CO)12BHAu2{AsPh3}2 and an investigation of the electrochemistry of Fe4(CO)12BHAu2L2, L  AsPh3 or PPh3

✍ Catherine E. Housecroft; Musa S. Shongwe; Arnold L. Rheingold; Piero Zanello 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 626 KB

Syntheses and characterization of cis-,

Syntheses and characterization of cis-, trans-mI[MoCl4py2] (MI = pyH+,Rb+,Cs+,N(CH3)+4,NH2(CH3)+2, PPh+4 and AsPh+4; py = pyridine) and the crystal structure of cis-Rb[MoCl4py2]·H2O

✍ J.V. Brencic; I. Leban; B. Modec 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 544 KB

LIGAND DISPLACEMENT REACTIONS FROM THE C

LIGAND DISPLACEMENT REACTIONS FROM THE COORDINATION SPHERE OF [CIS-CO(NH3)4(NO2)2]NO3: THE CRYSTAL AND MOLECULAR STRUCTURES OF [CIS-CO(NH3)4(OH)CL]CL (I) AND [CO(NH3)4(OXALATO)]2[TRANS-(NH3)(OH)CO(OXALATO)2]·4H2O (II)

✍ Bernal, Ivan; Cetrullo, James; Myrczek, Jozef 📂 Article 📅 1993 🏛 Taylor and Francis Group 🌐 English ⚖ 647 KB

Complexation of triangular faces of tetr

Complexation of triangular faces of tetranuclear clusters by the tripod ligands HC(PPh2)3 and HC(AsPh2)3. Molecular structure of (.pi.-toluene)[HC(PPh2)3]Co4(CO)6

✍ Bahsoun, A. A.; Osborn, J. A.; Voelker, C.; Bonnet, J. J.; Lavigne, G. 📂 Article 📅 1982 🏛 American Chemical Society 🌐 English ⚖ 1017 KB

Synthesis of iron carbonyl trimethylsila

Synthesis of iron carbonyl trimethylsilanes: preparations and interconversions of cis-(CO)4Fe[Si(CH3)3]2, M+[(CO)4FeSi(CH3)3]-, and trans- [Fe(CO)4Si(CH3)3]2

✍ Blakeney, Andrew J.; Johnson, Dennis Lee.; Donovan, Patrick W.; Gladysz, J. A. 📂 Article 📅 1981 🏛 American Chemical Society 🌐 English ⚖ 661 KB

Kinetic and structural studies of the re

Kinetic and structural studies of the reactions of phosphorous nucleophiles with the sulfido bimetallic clusters Cp'2Mo2Co2S3(CO)4 and Cp'2Mo2Co2S4(CO)2. X-ray crystal structure of Cp'2Mo2Co2S3(CO)4(PMe3)

✍ Curnow, Owen J.; Kampf, Jeff W.; Curtis, M. David; Shen, Jian-Kun; Basolo, Fred 📂 Article 📅 1994 🏛 American Chemical Society 🌐 English ⚖ 817 KB