The Crystal Structure of (3R,65)-3-Benzyl-4-Methyl-1, 4-Diaza-Bicyclo [4.4.0] Decan-2,5-Dione
β Scribed by M. van Poucke; A. T. H. Lenstra
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 229 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0037-9646
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β¦ Synopsis
Abstract
The piperidine ring in the title compound is in the chair conformation, whereas the diketopiperazine ring has a boat form. The benzyl group is axially positioned and folded above the diketopiperazine ring. No dimerisation is observed.
π SIMILAR VOLUMES
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5(4H)-ones / 2-Chloro-N-cyanomethyl-N-methylnicotinamide / Aromatic nucleophilic substitution A new synthesis of pyrido[3,2-f][1,4]thiazepine derivatives 3 starting with 2-chloronicotinic acid (1), methylaminoacetonitrile hydrochloride and carbon disulfide is described. As proved by a crystal struct