✦ LIBER ✦

A Facile Synthesis of Substituted 1,4-Benzothiazepin-5(4H)-ones and Pyrido[3,2-f][1,4]thiazepin-5(4H)-ones − Crystal and Molecular Structure of 2-Ethylthio-4-methyl-5(4H)-oxopyrido[3,2-f][1,4]thiazepine-3-carbonitrile

✍ Scribed by Wolfgang Dölling; Matthias Biedermann; Helmut Hartung

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 455 KB
Volume: 1998
Category: Article
ISSN: 1434-193X
DOI: 10.1002/(sici)1099-0690(199806)1998:6<1237::aid-ejoc1237>3.0.co;2-2

No coin nor oath required. For personal study only.

✦ Synopsis

5(4H)-ones / 2-Chloro-N-cyanomethyl-N-methylnicotinamide / Aromatic nucleophilic substitution A new synthesis of pyrido[3,2-f][1,4]thiazepine derivatives 3 starting with 2-chloronicotinic acid (1), methylaminoacetonitrile hydrochloride and carbon disulfide is described. As proved by a crystal structure determination, a boat conformation with approximated mirror symmetry can be assigned to the 1,4-thiazepine ring in 3b. 2-Chloro-N-cyanomethyl-Nmethyl-5-nitrobenzamide (5) reacts with carbon disulfide in

📜 SIMILAR VOLUMES

Syntheses and structures of new substitu

Syntheses and structures of new substituted 4-aryl-sulfonyl-4H-1,3,4-thiadiazin-5(6H)-ones

✍ Guofeng Jia; Zhengming Li 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 166 KB

The cyclization of 4-aryl-1-arylsulfonylthiosemicarbazides 3, which were prepared by treatment of arylsulfonyl chlorides 1 with 4-aryl-3-thiosemicarbazides 2, with chloroacetyl chloride, provided the corresponding 2-arylamino-4-arylsulfonyl-4H-1,3,4-thiadiazin-5(6H)-ones 4 in good yields. The struct

[1,2,4]Triazolo[1,2-a][1,2,4]triazole-1,

[1,2,4]Triazolo[1,2-a][1,2,4]triazole-1,3,5,7(2H,6H)-tetrone (Urazourazole), Synthesis and Structure

✍ Prof. Dr. Edgar Nachbaur; Gottfried Faleschini; Dr. Ferdinand Belaj; Prof. Dr. R 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 347 KB

Synthesis and X-Ray Diffraction Studies

Synthesis and X-Ray Diffraction Studies of Bis(4-propanoyl-2,4-dihydro-5-methyl-2-phenyl-3 H-pyrazol-3-onato) Dioxomolybdenum(VI) and [4-(1-trichloro-2-ethoxy)propanoyl-2,4-dihydro5-methyl-2-phenyl-3 H-pyrazol-3-onato][4-trichloroacetyl-2,4-dihydro5-methyl-2-phenyl-3 H-pyrazol-3-onato] Dioxomolybdenum(VI)

✍ Bieluonwu A. Uzoukwu; Karsten Gloe; Otto Rademacher 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 142 KB 👁 1 views

Preparation, Structure, and Reactivity o

Preparation, Structure, and Reactivity of 1,3,4-Triphenyl-4,5-dihydro-1H-1,2,4-triazol-5-ylidene, a New Stable Carbene

✍ Prof. Dr. Dieter Enders; Dipl.-Chem. Klaus Breuer; Dr. Gerhard Raabe; Dr. Jan Ru 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 386 KB

1H and 13C NMR spectroscopy of 6-aryl-su

1H and 13C NMR spectroscopy of 6-aryl-substituted 3-[5-methyl-1-(4-methylphenyl)-1,2,3-triazol-4-yl]-s-triazolo[3,4-b]-1,3,4-thiadiazoles

✍ Heng-Shan Dong; Bin Quan; Kun Wei; Qing-Lian Wang; Zi-Yi Zhang 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 1 views

Novel 6-aryl-3-[5-methyl-1-(4-methylphenyl)-1,2,3-triazol-4-yl]-s-triazolo[3,4-b]-1,3,4-thiadiazoles were synthesized by the condensation of 3-[5-methyl-1-(4-methylphenyl)-1,2,3-triazol-4-yl]-4amino-5-mercapto-s-triazole with various aromatic carboxylic acids in the presence of phosphorus oxychlorid

Dual Synthesis of 1H-[1,2,4]Triazolo[3,4

Dual Synthesis of 1H-[1,2,4]Triazolo[3,4-a]isoindoles and New 1H-[1,2,4]Triazolo[5,1-a]isoindoles − Experimental and Theoretical Approaches

✍ Patrice Woisel; Gheorghe Surpateanu; François Delattre; Marc Bria 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 328 KB