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The crystal chemistry of dense M3O4 polymorphs: High pressure Ca2GeO4 of K2NiF4 structure type

✍ Scribed by A.F. Reid; A.E. Ringwood

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
746 KB
Volume
1
Category
Article
ISSN
0022-4596

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new title compound are obtained from a mixture of La2O3, B2O3, and LaF3 in the molar ratio 5:6:2 (Walker-type multianvil apparatus, 6 GPa, 1300 Β°C, 10 min). La4B4O11F2 crystallizes in the monoclinic space group P21/c with Z = 8. The crystal structure contains BO3 groups connected by BO4 tetrahedra v