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The crystal and molecular structures of the trimethylphosphine–boron trihalide complexes: (CH3)3PBCl3, (CH3)3PBBr3 and (CH3)3PBI3

✍ Scribed by Black, D. L. ;Taylor, R. C.

Book ID
117859478
Publisher
International Union of Crystallography
Year
1975
Weight
514 KB
Volume
31
Category
Article
ISSN
0567-7408

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Optical absorption and magnetoabsorption spectra of the lead-halide-based perovskite-type crystals, CH 3 NH 3 PbX 3 (X ¼ Br, I) have been investigated. The lowest-energy excitons in these crystals are normal three-dimensional Wannier-type excitons. Bohr radii, binding energies, reduced masses, effec