Molecular structures of 2,2-dihalogenopropanes by microwave spectroscopy: CH3CF2CH3, CH3CCl2CH3, and CH3CClFCH3
β Scribed by Harutoshi Takeo; Masaaki Sugie; Chi Matsumura
- Book ID
- 107807432
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 415 KB
- Volume
- 352-353
- Category
- Article
- ISSN
- 0022-2860
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## Abstract Rate constants for the gasβphase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d
The structures ofcthylidcne and propylidene in their lowest singlet states :ue considered using INDO lnd MIND 112 calculations. Using a gadicnt optimization method, it is found that R!INDO/Z predicts no encrg minimu.n f-or singlet ethylidenc, while INDO predicts non-&ssic4 bridged structures for the