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The crystal and molecular structure of D-glucono-(1,5)-lactone

✍ Scribed by Hackert, M. L. ;Jacobson, R. A.


Book ID
117857194
Publisher
International Union of Crystallography
Year
1971
Weight
785 KB
Volume
27
Category
Article
ISSN
0567-7408

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The carbohydrate-derived lactone phenylsemicarbazones 3 and 4 were prepared from 5 and 8 (Scheme). Treatment with 4-phenylsemicarbazide gave 6 and 7 (77:23) and 9 and 10 (76:24), respectively. Oxidation of 6 and 9 by Cr0,-pyridine to 11 and 13, followed by deprotection, yielded 3 and 4. The structur