The crystal and molecular structure of bis-μ-oxo[2,2′-dipyridyl-oxohypophosphito molybdenum (V)]; A compound with monodentate hypophosphito ligands
✍ Scribed by Bryan M. Gatehouse; Ernest K. Nunn; Jaques E. Guerchais; Rene Kergoat
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 75 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0020-1650
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4
The X-ray crystal structures of 2,1l-bis(di-R-phosphinomethyl)benzo[c]phenanthrenes (R = Ph, t -Bu) are reported. Both ligands have the same conformation and the substitution of a Ph by a t -Bu group does not cause significant changes in the tetracyclic aromatic unit which shows the same distortions