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Synthesis and Investigations of the Crystal Structure of aDinuclear Diazadiene Molybdenum Oxo-Imido Complex with a Unique N3Mo(μ-O)2MoN3 Core

✍ Scribed by Alexei Merkoulov; Klaus Harms; Jörg Sundermeyer


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
115 KB
Volume
2005
Category
Article
ISSN
1434-1948

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Treating [Cp\*V(l-Cl) 2 ] 3 (Cp\* = C 5 Me 5 ) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoMe 2 ], respectively, with Me 3 SnF afforded the title compounds [Cp\*V(l-F) 2 ] 4 (1) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoF 2 ] ´THF ( 2). 1 has a tetrameric structure, in which four V atoms can be regarded as being arranged