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The crystal and molecular structure of 3,3,5,6-tetraphenyl-2,3-dihydro-1,4-oxathiin-2-one 4,4-dioxide

โœ Scribed by Yasuoka, N. ;Kasai, N. ;Tanaka, M. ;Nagai, T. ;Tokura, N.


Book ID
117858101
Publisher
International Union of Crystallography
Year
1972
Weight
692 KB
Volume
28
Category
Article
ISSN
0567-7408

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Electron impact induced fragmentation of
โœ Vesa Nevalainen; Pirjo Vainiotalo ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 709 KB

In the electron impact induced fragmentation of 2,3-disubstituted 5,6-dihydro-1,4-oxathiines, the cleavage of the heterocyclic ring proceeds through the retro Diels-Alder type of reaction. The further fragmentation of the resulting radical cation gives rise to substituted carbonyl or thiocarbonyl ca