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The Cracking and Rearrangement of Diallyl Ketals to α-Allyl Ketones

✍ Scribed by LORETTE, N. B.; HOWARD, W. L.

Book ID
127109961
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
467 KB
Volume
26
Category
Article
ISSN
0022-3263

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The dimers(La & b) of dimethyl-and diethylcyclopentadienone ketals(la & b) undergo a novel 1,3-alkoxy-rearrangement to 4\_(a & b). Mild hydrolysis of 2 or 3 gives the monoketones (?a or b). On strong acid catalysed hydrolysis 2, 5. or 4 afford the cyciopentadienone-dimer(6) In contrast to the notor