The kinetics of the photoinitiated copolymerization of styrene and methyl methacrylate in the presence of ethylaluminium sesquichloride, in toluene solution, has been investigated by dilatometry. The data are in agreement with a statistical copolymerization mechanism involving styrene and complexed
The copolymerization of methyl methacrylate and isoprene in the presence of ethyl aluminium sesquichloride: role of monomer complexes
β Scribed by J.R. Ebdon; N.P. Gabbott
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 764 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0032-3861
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Akstraet~opolymers of styrene (S) and methyl methacrylate (MMA) have been prepared with different concentrations of ethyl aluminium sesquichloride (EASC) using t3C-enriched forms of azo-bis-(methylisobutyrate) (AIBMe) and azo-bis-(isobutyronitrile) (AIBN). The end-group and overall structure of the
A~tract--The influence of the nature and acid strength of two complexing agents, AIEtCI 2 and A1Et2C1, on the alternating copolymerization of styrene and methyl methacrylate in toluene has been investigated. With AIEtC12, a cationic homopolymerization of styrene, which cannot be totally suppressed,