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The coordination chemistry of iminooxosulphuranes IX. The insertion reactions of tosyliminooxosulphurane with coordinatively unsaturated ruthenium and osmium aryl complexes

✍ Scribed by Max Herberhold; Anthony F. Hill


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
402 KB
Volume
395
Category
Article
ISSN
0022-328X

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The reactions of selected primary amines with the unsaturatedheterodimetallic complex[(η-C 5 Me 5 )Ni(¡-CO)Mo(CO) 2 -(η-C 5 H 5 )](Ni-ត Mo) (1a) were investigated. Primary amines react with this heterodimetallic complex to form unstable adducts, which are in equilibrium with the free amine and compl