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Reactions of coordinated tetrafluoroethylene with halogens. Synthesis of σ-bonded halotetrafluoroethyl complexes of ruthenium(II) and osmium(II) and the structure of OsI(C2F4I) (CO)2(PPh3)2

✍ Scribed by Anthony K. Burrell; George R. Clark; Clifton E.F. Rickard; Warren R. Roper; David C. Ware


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
680 KB
Volume
482
Category
Article
ISSN
0022-328X

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η4-Coordination of Dienes and Heterodien
✍ Rolf Rupp; Axel Frick; Gottfried Huttner; Peter Rutsch; Ute Winterhalter; Annett 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 649 KB

CH 3 C(CH 2 PPh 2 ) 3 CoCl (1) is easily accessible from CH 3 C(CH 2 PPh 2 ) 3 CoCl 2 by reduction with activated zinc powder. Upon dehalogenation with TlPF 6 , 1 reacts with dienes to give [tripodCo I -(η 4 -diene)] + (2). The heterodienes acrolein and methyl vinyl ketone produce the analogous η 4h