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The Cool-Flame Oxidation of 3-Ethylpentane

โœ Scribed by P. Barat, C. F. Cullis and R. T. Pollard

Book ID
123661420
Publisher
The Royal Society
Year
1971
Tongue
English
Weight
802 KB
Volume
325
Category
Article
ISSN
0962-8444

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The oxidation of 3-ethylpentane under Gifiv (and GoAggR) conditions affords, as major product, 3-acetylpentane and not diethylketone as previously mported. The discrepancy is explained by radical chain autoxidation in presence of a weak tertiary C-H bond The selective activation of saturated hydroca