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The Cool-Flame Oxidation of 3-Ethylpentane

โœ Scribed by Barat, P.; Cullis, C. F.; Pollard, R. T.

Book ID
120151662
Publisher
The Royal Society
Year
1971
Tongue
English
Weight
883 KB
Volume
325
Category
Article
ISSN
0962-8444

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The oxidation of 3-ethylpentane under Gifiv (and GoAggR) conditions affords, as major product, 3-acetylpentane and not diethylketone as previously mported. The discrepancy is explained by radical chain autoxidation in presence of a weak tertiary C-H bond The selective activation of saturated hydroca