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The Conversion of an Aziridine Plus an Iminium Salt to a 1,2-Diamine.

โœ Scribed by Matthew T. Hancock; Allan R. Pinhas


Book ID
101953390
Publisher
John Wiley and Sons
Year
2003
Weight
115 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


๐Ÿ“œ SIMILAR VOLUMES


The conversion of an aziridine plus an i
โœ Matthew T. Hancock; Allan R. Pinhas ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 173 KB

The conversion of an aziridine to a 1,2-diamine using lithium iodide and an iminium salt is discussed. We have found that when the aziridine is substituted by only alkyl groups, it is the less substituted carbon nitrogen bond that is broken; whereas, when the aziridine is substituted by a phenyl gro

A convenient and inexpensive conversion
โœ Matthew T. Hancock; Allan R. Pinhas ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 108 KB

The conversion of an aziridine to the corresponding oxazolidinone using only carbon dioxide and a catalytic amount of lithium iodide is discussed. In all cases, either no reaction occurred or a high yield of product was obtained. HMPA has been added to the reaction mixture, as needed, to drastically