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Conversion of an Aziridine to an Oxazolidinone Using a Salt and Carbon Dioxide in Water

✍ Scribed by Wallace, Justin R.; Lieberman, Deborah L.; Hancock, Matthew T.; Pinhas, Allan R.

Book ID
124091128
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
81 KB
Volume
82
Category
Article
ISSN
0021-9584

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πŸ“œ SIMILAR VOLUMES

A convenient and inexpensive conversion
A convenient and inexpensive conversion of an aziridine to an oxazolidinone
✍ Matthew T. Hancock; Allan R. Pinhas πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 108 KB

The conversion of an aziridine to the corresponding oxazolidinone using only carbon dioxide and a catalytic amount of lithium iodide is discussed. In all cases, either no reaction occurred or a high yield of product was obtained. HMPA has been added to the reaction mixture, as needed, to drastically

The high yield and regioselective conver
The high yield and regioselective conversion of an unactivated aziridine to an oxazolidinone using carbon dioxide with ammonium iodide as the catalyst
✍ Chau Phung; Allan R. Pinhas πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 167 KB

The conversion of an unactivated 2-alkylaziridine to the corresponding oxazolidinone generally requires a very high pressure of carbon dioxide, a high temperature, an expensive catalyst, and/or a long reaction time. Here, a new, high yield (over 95%), and highly regioselective (over 95%) conversion