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The contribution of hydrogen bonds to the surface tension of water

✍ Scribed by A. Luzar; S. Svetina; B. Žekš


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
435 KB
Volume
96
Category
Article
ISSN
0009-2614

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✦ Synopsis


The surface energy, the surface free energy and the surface entropy of liquid \cater are cakulated from the decrease in the number of hydrogen bonds in the surface layer, estimated on the basis of a simplified wafer structure scheme. In the calculations of the free energy density function only the hydrogen-bond interactions between molecules are taken into consideration. The resulting surface free energy of water is ==43 mNlm at 25°C. The calculated temperature dependence is consistent with that observed_


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