Perturbation of hydrogen bonding in water near polar surfaces
✍ Scribed by Roland Kjellander; Stjepan Marčelja
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 322 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0009-2614
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## Abstract Recent experiments indicate that the number of hydrogen bonds in solutions increases in the critical region of the solvent. This effect can be explained by the density fluctuations near the critical point. A theory of this unusual effect is developed. The theoretical predictions are com
The surface energy, the surface free energy and the surface entropy of liquid \cater are cakulated from the decrease in the number of hydrogen bonds in the surface layer, estimated on the basis of a simplified wafer structure scheme. In the calculations of the free energy density function only the h