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The conjugate addition-aldol tandem reaction of α,β-unsaturated esters catalyzed by lithium benzenethiolate

✍ Scribed by Masashi Ono; Katsumi Nishimura; Yasuo Nagaoka; Kiyoshi Tomioka

Book ID
108387346
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
246 KB
Volume
40
Category
Article
ISSN
0040-4039

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Efficient cyclization of ω-oxo-α,β-unsat
Efficient cyclization of ω-oxo-α,β-unsaturated esters using lithium thiolate-initiated Michael-aldol tandem reaction
✍ Masashi Ono; Katsumi Nishimura; Yasuo Nagaoka; Kiyoshi Tomioka 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 247 KB

The reaction of to-oxo-(x,13-unsaturated esters with lithium thiolates afforded the Michael-aldol tandem cyclization products in good to perfect stereoselectivity depending on the nature of thiolates.